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The Chemistry Portal

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Colourful solutions in test-tubes.
Welcome to the chemistry portal. Chemistry, from Greek language χυμεία meaning "study of liquids", is a branch of science. Modern chemistry focuses on the study of elements of the world and the bonds between elements. Chemistry also deals with composition, structure, and properties of substances and the transformations that they undergo. In the study of matter, chemistry also investigates its interactions with energy and itself. Because of the diversity of matter, which is mostly in the form of compounds, chemists often study how atoms of different chemical elements interact to form molecules, and how molecules interact with each other.


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Featured article - Selected picture - News - Selected biography - History and Philosophy - Techniques - Equipment - Chemistry in society - Chemistry in industry - Periodic Table - Resources - WikiProjects - Things you can do - Collaboration of the month - Related portals - Associated Wikimedia


  

Featured article

Ribbon diagram of phenylalanine hydroxylase, an enzyme which catalyses the reaction causing the addition of an hydroxyl group to the end of the 6-carbon aromatic ring of phenylalanine, such that it becomes tyrosine.
Enzymes are proteins that accelerate, or catalyze, chemical reactions. In these reactions, the molecules at the beginning of the process are called substrates and the enzyme converts these into different molecules: the products. Almost all processes in the cell need enzymes in order to occur at significant rates. Since enzymes are extremely selective for their substrates and speed up only a few reactions from among many possibilities, the set of enzymes made in a cell determines which metabolic pathways occur in that cell.

Enzymes are known to catalyze about 4,000 reactions. However, not all biological catalysts are proteins, since some RNA molecules called ribozymes can also catalyze reactions. Enzymes are usually named according to the reaction they catalyze. Typically the suffix -ase is added to the name of the substrate (e.g., lactase is the enzyme that cleaves lactose) or the type of reaction (e.g., DNA polymerase forms DNA polymers).

Like all catalysts, enzymes work by providing an alternative path of lower activation energy for a reaction and dramatically accelerating its rate. Some enzymes can make their conversion of substrate to product occur many millions of times faster. For example, the reaction catalysed by orotidine 5'-phosphate decarboxylase will consume half of its substrate in 78 million years if no enzyme is present. However, when the decarboxylase is added, the same process takes just 25 milliseconds. Chemically, enzymes are like any catalyst and are not consumed in chemical reactions, nor do they alter the equilibrium of a reaction. However, enzymes do differ from most other catalysts by being much more specific.

Enzyme activity can be affected by other molecules. Inhibitors are molecules that decrease enzyme activity, and activators are molecules that increase activity. Drugs and poisons are often enzyme inhibitors.

Some enzymes are used commercially, for example, in the synthesis of antibiotics. In addition, some household cleaning products use enzymes to speed up chemical reactions (e.g., enzymes in biological washing powders break down protein or fat stains on clothes).

  

Selected picture

Meitner and Hahn
Credit: United States Department of Energy

Chemist Otto Hahn and physicist Lise Meitner collaborated on radiochemistry for thirty years in Berlin. In 1918 they discovered the first long-lived isotope of protactinium, and they are also both credited for the 1938 discovery of nuclear fission. Hahn went on to win the 1944 Nobel Prize for Chemistry alone, but Meitner is regarded as having provided the explanation for Hahn's observations. Meitner had fled Nazi Germany in 1938, preventing joint publication. She is now commemorated in element no. 109, meitnerium.

  

Categories

  

History and Philosophy of Chemistry

Antoine Lavoisier

Many chemists have an interest in the history of chemistry. Those with philosophical interests will be interested that the philosophy of chemistry has quite recently developed along a path somewhat different from the general philosophy of science.

Other articles that might interest you are:

There is a Wikipedia Project on the History of Science and portals for the scientific method and philosophy of science.

  

Chemistry Resources

Wikipedia:WikiProject Chemicals/Data is a collection of links and references that are useful for chemistry-related works. This includes free online chemical databases, publications, patents, computer programs, and various tools.

Science is Fun University of Wisconsin-Madison Chemistry Professor Bassam Z. Shakhashiri, shares the fun of science.

megaConverter The Web's best place to figure out what equals what.

General Chemistry Online Clear text and comprehensive coverage of general chemistry topics by Fred Senese, Dept. of Chemistry Frostburg State University

General Chemistry Demonstration at Purdue Video clips (and descriptions) of lecture demonstrations.

Intota Chemistry Experts A large online listing of real-world chemistry expert biographies provides examples of the many areas of expertise and careers in chemistry.

Chemistry Webercises Directory A large listing of chemistry resources maintained by Steven Murov, Emeritus Chemistry Professor Modesto Junior College.

MathMol MathMol (Mathematics and Molecules) is a good starting point for those interested in the field of molecular modeling.

Chemistry Educational Resources and Essential References from Wiley, the world's largest chemistry publisher

ABC Chemistry A directory of free full-text journals in chemistry, biochemistry and related subjects.

  

In the news

Rohm and Haas Headquarters in 2007.
Rohm and Haas Headquarters in 2007.
  • 7-10 US chemical giant Dow Chemical has announced that it is to buy Philadelphia-based rival Rohm and Haas. Dow is paying $78 per share, a 74 percent premium, which makes the agreement worth around $15.3 billion. The change will expand Dow's presence in the specialty chemical market. Dow plans to set up an advanced materials business unit at the Rohm and Haas headquarters in Philadelphia, and this unit will retain the Rohm and Haas name. Read more...
  • 2-15 Chemists modeling the structure of strongly acidic solutions have found that hydronium ions can associate into unusual ion pairs. Gregory A. Voth and Sergei Izvekov of the University of Utah, in collaboration with Feng Wang of Boston University, were examining the structure of aqueous hydrochloric acid at concentrations of 0.43-0.85 M, and they found that the ions unexpectedly associate into pairs. See doi:10.1021/ja078106i Read more...
  

Selected biography

Hermann Emil Fischer
Hermann Emil Fischer (1852-1919) was a German chemist, and recipient of the Nobel Prize for Chemistry in 1902. Many consider Fischer to be the most brilliant chemist who ever lived, because of his numerous contributions to science, especially chemistry and biochemistry. Among these is his discovery of phenylhydrazine. He also undertook vast studies on purines. This work showed that various substances such as adenine, xanthine, caffeine, uric acid, and guanine, all belonged to one homogeneous family, and could be derived from one another. He reasoned this to be due to their common origins from a parent molecule, a bicyclic nitrogenous structure into which the characteristic urea group entered. Fischer regarded this structure as hypothetical, and named it 'purine' in 1884. He synthesised it in 1898. He is also famed for his work on sugars.
  

Techniques used by chemists

  

Equipment used by chemists

  

Chemistry in society

  

Chemistry in industry

  

WikiProjects

  

Periodic Table

  

Things you can do

Here are some things you can do:

  

Collaboration of the Month

The current Chemistry Collaboration of the Month is Catalysis.
Every month a different chemistry-related topic, stub or non-existent article is picked. Please improve the article any way you can.
  

Related portals

  

Associated Wikimedia

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